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V
| Player | Bats | Throws | Position | Team | Data |
|---|---|---|---|---|---|
| Valaika, Chris | - | R | 2B | Cincinnati Reds | pitcher | batter |
| Valbuena, Luis | - | R | 2B | Cleveland Indians | pitcher | batter |
| Valdes, Raul | - | L | P | New York Mets | pitcher | batter |
| Valdez, Cesar | - | R | P | Arizona Diamondbacks | pitcher | batter |
| Valdez, Jose | - | R | P | Houston Astros | pitcher | batter |
| Valdez, Luis | - | R | P | Atlanta Braves | pitcher | batter |
| Valdez, Merkin | - | R | P | Toronto Blue Jays | pitcher | batter |
| Valdez, Wilson | - | R | SS | Philadelphia Phillies | pitcher | batter |
| Valencia, Danny | - | R | 3B | Minnesota Twins | pitcher | batter |
| Valentin, Javier | - | R | DH | pitcher | batter | |
| Valiquette, Philippe | - | L | P | Cincinnati Reds | pitcher | batter |
| Vallejo, Jose | - | R | 2B | Houston Astros | pitcher | batter |
| Valverde, Jose | - | R | P | Detroit Tigers | pitcher | batter |
| Van Benschoten, John | - | R | DH | pitcher | batter | |
| Van Every, Jonathan | - | L | CF | Boston Red Sox | pitcher | batter |
| Van Mil, Loek | - | R | P | Minnesota Twins | pitcher | batter |
| VandenHurk, Rick | - | R | P | Baltimore Orioles | pitcher | batter |
| Vargas, Claudio | - | R | P | Milwaukee Brewers | pitcher | batter |
| Vargas, Jason | - | L | P | Seattle Mariners | pitcher | batter |
| Varitek, Jason | - | R | C | Boston Red Sox | pitcher | batter |
| Varvaro, Anthony | - | R | P | Seattle Mariners | pitcher | batter |
| Vasquez, Esmerling | - | R | P | Arizona Diamondbacks | pitcher | batter |
| Vasquez, Virgil | - | R | P | Pittsburgh Pirates | pitcher | batter |
| Vazquez, Javier | - | R | P | New York Yankees | pitcher | batter |
| Vazquez, Ramon | - | R | SS | Pittsburgh Pirates | pitcher | batter |
| Veal, Donald | - | L | P | Pittsburgh Pirates | pitcher | batter |
| Vega, Marwin | - | R | P | Seattle Mariners | pitcher | batter |
| Velandia, Jorge | - | R | DH | pitcher | batter | |
| Velazquez, Gil | - | R | DH | pitcher | batter | |
| Velez, Eugenio | - | R | LF | San Francisco Giants | pitcher | batter |
| Venable, Will | - | L | RF | San Diego Padres | pitcher | batter |
| Venters, Jonny | - | L | P | Atlanta Braves | pitcher | batter |
| Veras, Jose | - | R | P | Florida Marlins | pitcher | batter |
| Verlander, Justin | - | R | P | Detroit Tigers | pitcher | batter |
| Vern, Matt | - | R | DH | pitcher | batter | |
| Viciedo, Dayan | - | R | 3B | Chicago White Sox | pitcher | batter |
| Victorino, Shane | - | R | CF | Philadelphia Phillies | pitcher | batter |
| Vidro, Jose | - | R | DH | pitcher | batter | |
| Villalona, Angel | - | R | DH | pitcher | batter | |
| Villanueva, Carlos | - | R | P | Milwaukee Brewers | pitcher | batter |
| Villar, Henry | - | R | P | Houston Astros | pitcher | batter |
| Villarreal, Oscar | - | R | DH | pitcher | batter | |
| Villone, Ron | - | L | P | Washington Nationals | pitcher | batter |
| Viola, Pedro | - | L | P | Baltimore Orioles | pitcher | batter |
| Vizcaino, Luis | - | R | DH | pitcher | batter | |
| Vizquel, Omar | - | R | 3B | Chicago White Sox | pitcher | batter |
| Volquez, Edinson | - | R | P | Cincinnati Reds | pitcher | batter |
| Volstad, Chris | - | R | P | Florida Marlins | pitcher | batter |
| Votto, Joey | - | R | 1B | Cincinnati Reds | pitcher | batter |